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GHS Hazard statement

H-phrases

  H200 Unstable explosive
  H201 Explosive; mass explosion hazard
  H202 Explosive; severe projection hazard
  H203 Explosive; fire, blast or projection hazard
  H204 Fire or projection hazard
  H205 May mass explode in fire
  H220 Extremely flammable gas
  H221 Flammable gas   H222 Extremely flammable aerosol
  H223 Flammable aerosol
  H224 Extremely flammable liquid and vapour
  H225 Highly flammable liquid and vapour
  H226 Flammable liquid and vapour
  H227 Combustible liquid
  H228 Flammable solid
  H229 Pressurized container: may burst if heated
  H230 May react explosively even in the absence of air
  H231 May react explosively even in the absence of air at elevated pressure
           and/or temperature
  H240 Heating may cause an explosion
  H241 Heating may cause a fire or explosion
  H242 Heating may cause a fire
  H250 Catches fire spontaneously if exposed to air
  H251 Self-heating; may catch fire
  H252 Self-heating in large quantities; may catch fire
  H260 In contact with water releases flammable gases which may ignite
           spontaneously
  H261 In contact with water releases flammable gas
  H270 May cause or intensify fire; oxidizer
  H271 May cause fire or explosion; strong oxidizer
  H272 May intensify fire; oxidizer
  H280 Contains gas under pressure; may explode if heated
  H281 Contains refrigerated gas; may cause cryogenic burns or injury
  H290: May be corrosive to metals

Health hazards

  H300 Fatal if swallowed
  H301 Toxic if swallowed
  H302 Harmful if swallowed
  H303 May be harmful if swallowed
  H304 May be fatal if swallowed and enters airways
  H305 May be harmful if swallowed and enters airways
  H310 Fatal in contact with skin
  H311 Toxic in contact with skin
  H312 Harmful in contact with skin
  H313 May be harmful in contact with skin
  H314 Causes severe skin burns and eye damage
  H315 Causes skin irritation
  H316 Causes mild skin irritation
  H317 May cause an allergic skin reaction
  H318 Causes serious eye damage
  H319 Causes serious eye irritation
  H320 Causes eye irritation
  H330 Fatal if inhaled
  H331 Toxic if inhaled
  H332 Harmful if inhaled
  H333 May be harmful if inhaled
  H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled
  H335 May cause respiratory irritation
  H336 May cause drowsiness or dizziness
  H340 May cause genetic defects
  H341 Suspected of causing genetic defects
  H350 May cause cancer
  H351 Suspected of causing cancer
  H360 May damage fertility or the unborn child
  H361 Suspected of damaging fertility or the unborn child
  H362 May cause harm to breast-fed children
  H370 Causes damage to organs
  H371 May cause damage to organs
  H372 Causes damage to organs through prolonged or repeated exposure
  H373 May cause damage to organs through prolonged or repeated exposure

Environmental hazards

  H400 Very toxic to aquatic life
  H401 Toxic to aquatic life
  H402 Harmful to aquatic life
  H410 Very toxic to aquatic life with long lasting effects
  H411 Toxic to aquatic life with long lasting effects
  H412 Harmful to aquatic life with long lasting effects
  H413 May cause long lasting harmful effects to aquatic life
  H420 Harms public health and the environment by destroying ozone in the
            upper atmosphere

Country-specific hazard statements
European Union




  EUH001 Explosive when dry
  EUH006 Explosive with or without contact with air
  EUH014 Reacts violently with water
  EUH018 In use may form flammable/explosive vapour-air mixture
  EUH019 May form explosive peroxides
  EUH044 Risk of explosion if heated under confinement

Health properties

  EUH029 Contact with water liberates toxic gas
  EUH031 Contact with acids liberates toxic gas
  EUH032 Contact with acids liberates very toxic gas
  EUH066 Repeated exposure may cause skin dryness or cracking
  EUH070 Toxic by eye contact
  EUH071: Corrosive to the respiratory tract

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

P-phrases

General precautionary statements

P101 If medical advice is needed, have product container or label at hand
P102 Keep out of reach of children
P103 Read label before use
P201 Obtain special instructions before use
P202 Do not handle until all safety precautions have been read and understood
P210 Keep away from heat/sparks/open flames/hot surfaces – No smoking
P211 Do not spray on an open flame or other igntion source
P220 Keep/Store away from clothing/.../combustible materials
P221 Take any precaustion to avoid mixinn with combustibles
P222 Do not allow contact with air
P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire
P230 Keep wetted with ...
P231 Handle under inert gas
P232 Protect from moisture
P233 Keep container tightly closed
P234 Keep only in original container
P235 Keep cool
P240 Ground/bond container and receiving equipment
P241 Use explosion-proof electrical/ventilating/light/.../equipment
P242 Use only non-sparking tools
P243 Take precautionary measures against static discharge
P244 Keep reduction valves free from grease and oil
P250 Do not subject to grinding/shock/.../friction
P251 Pressurized container– Do not pierce or burn, even after use
P260 Do not breathe dust/fume/gas/mist/vapours/spray
P261 Avoid breathing dust/fume/gas/mist/vapours/spray
P262 Do not get in eyes, on skin, or on clothing
P263 Avoid contact during pregnancy/while nursing
P264 Wash ... thoroughly after handling
P270 Do not eat,drink or smoke when using this product
P271 Use only outdoors or in a well-ventilated area
P272 Contaminated work clothing should not be allowed out of the workplace
P273 Avoid release to the environment
P280 Wear protective gloves/protective clothing/eye protection/face protection
P281 Use personal protective equipment as required
P282 Wear cold insulating gloves/face shield/eye protection
P283 Wear fire/flame resistant/retardant clothing
P284 Wear respiratory protection
P285 In case of inadequateventilation wear respiratory protection
P231+232 Handle under inert gas. Protect from moisture
P235+410 Keep cool. Protect from sunlight

Response precautionary statements

P301 IF SWALLOWED:
P302 IF ON SKIN:
P303 IF ON SKIN (or hair):
P304 IF INHALED:
P305 IF IN EYES:
P306 IF ON CLOTHING:
P307 IF exposed:
P308 IF exposed or concerned:
P309 IF exposed or you feel unwell:
P310 Immediately call a POISON CENTER or doctor/physician
P311 Call a POISON CENTER or doctor/physician
P312 Call a POISON CENTER or doctor/physician if you feel unwell
P313 Get medical advice/attention
P314 Get Medical advice/attention if you feel unwell
P315 Get immediate medical advice/attention
P320 Specific treatment is urgent (see ... on this label)
P321 Specific treatment (see ... on this label)
P322 Specific measures (see ... on this label)
P330 Rinse mouth
P331 Do NOT induce vomiting
P332 If skin irritation occurs:
P333 If skin irritation or a rash occurs:
P334 Immerse in cool water/wrap in wet bandages
P335 Brush off loose particles from skin
P336 Thaw frosted parts with lukewarm water. Do not rub affected areas
P337 If eye irritation persists
P338 Remove contact lenses if present and easy to do. continue rinsing
P340 Remove victim to fresh air and keep at rest in a position comfortable for breathing
P341 If breathing is difficult, remove victim to fresh air and keep at rest in a positioncomfortable for breathing
P342 If experiencing respiratory symptoms:
P350 Gently wash with soap and water
P351 Rinse continuously with water for several minutes
P352 Wash with soap and water
P353 Rinse skin with water/shower
P360 Rinse immediately contaminated clothing and skin with plenty of water beforeremoving clothes
P361 Remove/Take off immediately all contaminated clothing
P362 Take off contaminated clothing and wash before reuse
P363 Wash contaminated clothing before reuse
P370 In case of fire:
P371 In case of major fire and large quantities:
P372 Explosion risk in case of fire
P373 DO NOT fight fire when fire reaches explosives
P374 Fight fire with normal precautions from a reasonable distance
P375 Fight fire remotely due to the risk of explosion
P376 Stop leak if safe to do so
P377 Leaking gas fire – do not extinguish unless leak can be stopped safely
P378 Use ... for extinction
P380 Evacuate area
P381 Eliminate all ignition sources if safe to do so
P390 Absorb spillage to prevent material damage
P391 Collect spillagee
P301+310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician
P301+312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell
P301+330+331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting
P302+334 IF ON SKIN: Immerse in cool water/wrap in wet bandages
P302+350 IF ON SKIN: Gently wash with soap and water
P302+352 IF ON SKIN: Wash with soap and water
P303+361+353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing.Rinse skin with water/shower
P304+312 IF INHALED: Call a POISON CENTER or doctor/physician if you feel unwell
P304+340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P304+341 IF INHALED: If breathing is difficult, remove victim to fresh air and keep atrest in a position comfortable for breathing
P305+351+338 IF IN EYES: Rinse continuously with water for several minutes. Remove contact lenses if present and easy to do – continue rinsing
P306+360 IF ON CLOTHING: Rinse immediately contaminated clothing and skin with plenty of water before removing clothes
P307+311 IF exposed: Call a POISON CENTER or doctor/physician
P308+313 IF exposed or concerned: Get medical advice/attention
P309+311 IF exposed or you feel unwell: Call a POISON CENTER or doctor/physician
P332+313 IF skin irritation occurs: Get medical advice/attention
P333+313 IF skin irritation or a rash occurs: Get medical advice/attention
P335+334 Brush off loose particles from skin.Immerse in cool water/wrap in wet bandages
P337+313 Get medical advice/attention
P342+311 Call a POISON CENTER or doctor/physician
P370+376 In case of fire: Stop leak if safe to do so
P370+378 In case of fire: Use ... for extinction
P370+380 In case of fire: Evacuate area
P370+380+375 In case of fire: Evacuate area. Fight fire remotely due to the risk of explosion
P371+380+375 In case of major fire and large quantities: Evacuate area. Fight fire remotely dueto the risk of explosion

Storage precautionary statements
P401 Store ...
P402 Store in a dry place
P403 Store in a well ventilated place
P404 Store in a closed container
P405 Store locked up
P406 Store in a corrosive resistant/... container with a resistant inner liner
P407 Maintain air gap between stacks/pallets
P410 Protect from sunlight
P411 Store at temperatures not exceeding ...°C/... °F
P412 Do not expose to temperatures exceeding 50 °C/122 °F
P420 Store away from other materials
P422 Store contents under ..
P402 + 404 Store in a dry place. Store in aclosed container
P403 + 233 Store in a well ventilated place.Keep container tightly closed
P403 + 235 Store in a well ventilated place.Keep cool
P410 + 403 Protect from sunlight. Store in a well ventilated place
P410 + 412 Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F
P411 + 235 Store at temperatures not exceeding ...°C/... °F. Keep cool

Disposal precautionary statements
P501 Dispose of contents/container to ...

R-phrases

R1 Explosive when dry
R2 Risk of explosion by shock, friction, fire or other sources of ignition
R3 Extreme risk of explosion by shock, friction, fire or other sources of ignition
R4 Forms very sensitive explosive metallic compounds
R5 Heating may cause an explosion
R6 Explosive with or without contact with air
R7 May cause fire
R8 Contact with combustible material may cause fire
R9 Explosive when mixed with combustible material
R10 Flammable
R11 Highly flammable
R12 Extremely flammable
R14 Reacts violently with water
R15 Contact with water liberates extremely flammable gases
R16 Explosive when mixed with oxidising substances
R17 Spontaneously flammable in air
R18 In use, may form flammable/explosive vapour-air mixture
R19 May form explosive peroxides
R20 Harmful by inhalation
R21 Harmful in contact with skin
R22 Harmful if swallowed
R23 Toxic by inhalation
R24 Toxic in contact with skin
R25 Toxic if swallowed
R26 Very toxic by inhalation
R27 Very toxic in contact with skin
R28 Very toxic if swallowed
R29 Contact with water liberates toxic gas.
R30 Can become highly flammable in use
R31 Contact with acids liberates toxic gas
R32 Contact with acids liberates very toxic gas
R33 Danger of cumulative effects
R34 Causes burns
R35 Causes severe burns
R36 Irritating to eyes
R37 Irritating to respiratory system
R38  Irritating to skin
R39 Danger of very serious irreversible effects
R40 Limited evidence of a carcinogenic effect
R41 Risk of serious damage to eyes
R42 May cause sensitisation by inhalation
R43 May cause sensitisation by skin contact
R44 Risk of explosion if heated under confinement
R45 May cause cancer
R46 May cause inheritable genetic damage
R48 Danger of serious damage to health by prolonged exposure
R49 May cause cancer by inhalation
R50 Very toxic to aquatic organisms
R51 Toxic to aquatic organisms
R52 Harmful to aquatic organisms
R53 May cause long-term adverse effects in the aquatic environment
R54 Toxic to flora
R55  Toxic to fauna
R56  Toxic to soil organisms
R57  Toxic to bees
R58 May cause long-term adverse effects in the environment
R59 Dangerous for the ozone layer
R60 May impair fertility
R61 May cause harm to the unborn child
R62 Possible risk of impaired fertility
R63 Possible risk of harm to the unborn child
R64 May cause harm to breast-fed babies
R65 Harmful: may cause lung damage if swallowed
R66 Repeated exposure may cause skin dryness or cracking
R67 Vapours may cause drowsiness and dizziness
R68 Possible risk of irreversible effects


Combinations
Code Combination     Statement


R14/15 Reacts violently with water, liberating extremely flammable  gases
R15/29 Contact with water liberates toxic, extremely flammable gases
R14/15/29 Reacts violently with water, liberating toxic, extremely flammable gases
R20/21 Harmful by inhalation and in contact with skin
R20/22 Harmful by inhalation and if swallowed
R20/21/22 Harmful by inhalation, in contact with skin and if swallowed
R21/22  Harmful in contact with skin and if swallowed
R23/24 Toxic by inhalation and in contact with skin
R23/25 Toxic by inhalation and if swallowed
R23/24/25 Toxic by inhalation, in contact with skin and if swallowed
R24/25 Toxic in contact with skin and if swallowed
R26/27 Very toxic by inhalation and in contact with skin
R26/28 Very toxic by inhalation and if swallowed
R26/27/28 Very toxic by inhalation, in contact with skin and if swallowed
R27/28 Very toxic in contact with skin and if swallowed
R36/37 Irritating to eyes and respiratory system
R36/38 Irritating to eyes and skin
R36/37/38 Irritating to eyes, respiratory system and skin
R37/38 Irritating to respiratory system and skin
R39/23 Toxic: danger of very serious irreversible effects throughinhalation
R39/24 Toxic: danger of very serious irreversible effects in contact with skin
R39/25 Toxic: danger of very serious irreversible effects if swallowed
R39/23/24 Toxic: danger of very serious irreversible effects through inhalation and in contact with skin
R39/23/25 Toxic: danger of very serious irreversible effects through inhalation and if swallowed
R39/24/25 Toxic: danger of very serious irreversible effects in contact with skin and if swallowed
R39/23/24/25 Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed
R39/26 Very Toxic: danger of very serious irreversible effects through inhalation
R39/27 Very Toxic: danger of very serious irreversible effects in contact with skin
R39/28 Very Toxic: danger of very serious irreversible effects if swallowed
R39/26/27 Very Toxic: danger of very serious irreversible effects through inhalation and in contact with skin
R39/26/28 Very Toxic: danger of very serious irreversible effects through inhalation and if swallowed
R39/27/28 Very Toxic: danger of very serious irreversible effects in contact with skin and if swallowed
R39/26/27/28 Very Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed
R42/43 May cause sensitization by inhalation and skin contact
R45/46 May cause cancer and heritable genetic damage
R48/20 Harmful: danger of serious damage to health by prolonged exposure through inhalation
R48/21 Harmful: danger of serious damage to health by prolonged exposure in contact with skin
R48/22 Harmful: danger of serious damage to health by prolonged exposure if swallowed
R48/20/21Harmful: danger of serious damage to health by prolonged exposure through inhalation and in contact with skin
R48/20/22 Harmful: danger of serious damage to health by prolonged exposure through inhalation and if swallowed
R48/21/22 Harmful: danger of serious damage to health by prolonged exposure in contact with skin and if swallowed
R48/20/21/22 Harmful: danger of serious damage to health by prolonged exposure through inhalation, in contact with skin and if swallowed
R48/23 Toxic: danger of serious damage to health by prolonged exposure through inhalation
R48/24 Toxic: danger of serious damage to health by prolonged exposure in contact with skin
R48/25 Toxic: danger of serious damage to health by prolonged exposure if swallowed
R48/23/24 Toxic: danger of serious damage to health by prolonged exposure through inhalation and in contact with skin
R48/23/25 Toxic: danger of serious damage to health by prolonged exposure through inhalation and if swallowed
R48/24/25 Toxic: danger of serious damage to health by prolonged exposure in contact with skin and if swallowed
R48/23/24/25 Toxic: danger of serious damage to health by prolonged exposure through inhalation, in contact with skin and if swallowed
R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment
R68/20 Harmful: possible risk of irreversible effects through inhalation
R68/21Harmful: possible risk of irreversible effects in contact with skin
R68/22 Harmful: possible risk of irreversible effects if swallowed
R68/20/21 Harmful: possible risk of irreversible effects through inhalation and in contact with skin
R68/20/22 Harmful: possible risk of irreversible effects through inhalation and if swallowed
R68/21/22  Harmful: possible risk of irreversible effects in contact with skin and if swallowed
R68/20/21/22 Harmful: possible risk of irreversible effects through inhalation, in contact with skin and if swallowed

 

S-phrases

S1 Keep locked up
S2 Keep out of the reach of children
S3 Keep in a cool place
S4 Keep away from living quarters
S5 Keep contents under ... (appropriate liquid to be specified by the manufacturer)
S6 Keep under ... (inert gas to be specified by the manufacturer)
S7 Keep container tightly closed
S8 Keep container dry
S9 Keep container in a well-ventilated place
S10 Keep contents wet
S11 not specified
S12 Do not keep the container sealed
S13 Keep away from food, drink and animal foodstuffs
S14 Keep away from ... (incompatible materials to be indicated by the manufacturer)
S15 Keep away from heat
S16 Keep away from sources of ignition - No smoking
S17 Keep away from combustible material
S18 Handle and open container with care
S20 When using do not eat or drink
S21When using do not smoke
S22 Do not breathe dust
S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer)
S24 Avoid contact with skin
S25 Avoid contact with eyes
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
S27 Take off immediately all contaminated clothing
S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer)
S29 Do not empty into drains
S30 Never add water to this product
S33 Take precautionary measures against static discharges
S35 This material and its container must be disposed of in a safe way
S36 Wear suitable protective clothing
S37 Wear suitable gloves
S38 In case of insufficient ventilation wear suitable respiratory equipment
S39 Wear eye/face protection
S40 To clean the floor and all objects contaminated by this material use ... (to be specified by the manufacturer)
S41 In case of fire and/or explosion do not breathe fumes
S42 During fumigation/spraying wear suitable respiratory equipment (appropriate wording to be specified by the manufacturer)
S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add - Never use water)
S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible)
S46 If swallowed, seek medical advice immediately and show this container or label
S47 Keep at temperature not exceeding ... °C (to be specified by the manufacturer)
S48 Keep wet with ... (appropriate material to be specified by the manufacturer)
S49 Keep only in the original container
S50 Do not mix with ... (to be specified by the manufacturer)
S51 Use only in well-ventilated areas
S52 Not recommended for interior use on large surface areas
S53 Avoid exposure - obtain special instructions before use
S56 Dispose of this material and its container at hazardous or special waste collection point
S57 Use appropriate containment to avoid environmental contamination
S59 Refer to manufacturer/supplier for information on recovery/recycling
S60 This material and its container must be disposed of as hazardous waste
S61 Avoid release to the environment. Refer to special instructions / safety data sheet
S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label where possible
S63 In case of accident by inhalation: remove casualty to fresh air and keep at rest
S64 If swallowed, rinse mouth with water (only if the person is
 conscious)
(S1/2) Keep locked up and out of the reach of children
S3/7 Keep container tightly closed in a cool place
S3/7/9 Keep container tightly closed in a cool, well-ventilated place
S3/9/14 Keep in a cool, well-ventilated place away from ... (incompatible materials to be indicated by the manufacturer)
S3/9/14/49 Keep only in the original container in a cool, well-ventilated place away from ... (incompatible materials to be indicated by the manufacturer)
S3/9/49 Keep only in the original container in a cool, well-ventilated place
S3/14 Keep in a cool place away from ... (incompatible materials to be indicated by the manufacturer)
S7/8 Keep container tightly closed and dry
S7/9 Keep container tightly closed and in a well-ventilated place
S7/47 Keep container tightly closed and at temperature not exceeding ... °C (to be specified by the manufacturer)
S8/10 Keep container wet, but keep the contents dry
S20/21When using do not eat, drink or smoke
S24/25 Avoid contact with skin and eyes
S27/28 After contact with skin, take off immediately all contaminated clothing, and wash immediately with plenty of ... (to be specified by the manufacturer)
S29/35 Do not empty into drains; dispose of this material and its container in a safe way
S29/56 Do not empty into drains, dispose of this material and its container at hazardous or special waste collection point
S36/37 Wear suitable protective clothing and gloves
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection
S36/39 Wear suitable protective clothing and eye/face protection
S37/39 Wear suitable gloves and eye/face protection
S47/49 Keep only in the original container at temperature not exceeding ... °C (to be specified by the manufacturer)